UNION CARBIDE CORP LINDE DIV -- ISOPROPANOL ANHYDROUS -- 6810-00-753-4993
===================== Product Identification ===================== Product ID:ISOPROPANOL ANHYDROUS MSDS Date:08/10/1998 FSC:6810 NIIN:00-753-4993 Status Code:A === Responsible Party === Company Name:UNION CARBIDE CORP LINDE DIV Address:39 OLD RIDGEBURY RD City:DANBURY State:CT ZIP:06817-0001 Country:US Info Phone Num:800-822-4357; 304-744-3487 Emergency Phone Num:800-822-4357 Resp. Party Other MSDS Num.:000000001194 CAGE:36346 === Contractor Identification === Company Name:UNION CARBIDE CORP LINDE DIV Address:39 OLD RIDGEBURY RD Box:City:DANBURY State:CT ZIP:06817-0001 Country:US Phone:800-822-4357; 304-744-3487 CAGE:36346 ============= Composition/Information on Ingredients ============= Ingred Name:ISOPROPANOL CAS:67-63-0 RTECS #:NT8050000 = Wt:100. OSHA PEL:980 MG/M3;400 PPM OSHA STEL:1225 MG/M3,500 PPM ACGIH TLV:983 MG/M3;400 PPM ACGIH STEL:1230 MG/M3;500 PPM ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Health Hazards Acute and Chronic:ACUTE:INHALATION: HIGH CONCENTRATIONS OF VAPOR MAY CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION, WITH LOSS OF CONSCIOUSNESS. VAPOR CAUSES IRRITATION OF RESPIRATORY TRACT. EYE CONTACT: CAUSES IRRITATION, CO RNEAL INJURY. SKIN CONTACT: MAY CAUSE MINOR IRRITATION. PROLONGED OR REPEATED CONTACT MAY CAUSE DEFATTING AND DRYING OF SKIN. SKIN ABSORPTION: EXPOSURE TO SMALL QUANTITIES IS NOT EXPECTED TO CAUSE AD VERSE HEALTH EFFECTS. PROLONGED EXPOSURE MAY RESULT IN ABSORPTION OF HARMFUL AMOUNTS, PARTICULARLY IN INFANTS. SWALLOWING: SLIGHTLY TOXIC. MAY CAUSE DIZZINESS. CHRONIC: PROLONGED OR REPEATED SKIN EXPO SURE CAN CAUSE DEFATTING. Explanation of Carcinogenicity:NO EVIDENCE SUGGESTIVE OF CARCINOGENIC ACTIVITY WAS NOTED IN CHRONIC VAPOR INHALATION STUDIES WITH ISOPROPANOL IN RATS AND MICE. Effects of Overexposure:INHALATION: CNS DEPRESSION, WEAKNESS, DROWSINESS, LOSS OF CONSCIOUSNESS, RESPIRATORY TRACT IRRITATION, COUGHING, CHEST DISCOMFORT. EYE CONTACT: IRRITATION, STINGING, DISCOMFORT, PAIN, CORNEAL INJURY. SKIN CONTACT: IRRITATION, ITCHING, REDNESS, DEFATTING, DRYING. SKIN ABSORPTION: ADVERSE HEALTH EFFECTS, SAME SIGNS AS FOR INGESTION. INGESTION: DIZZINESS, FAINTNESS, DROWSINESS, DECREASED AWARENESS AN D RESPONSIVENESS, LACK OF COORDINATION, ABDOMINAL DISCOMFORT, NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN EXISTING DERMATITIS. ======================= First Aid Measures ======================= First Aid:INHALATION: MOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT BREATHING. IF BREATHING DIFFICULT, GIVE OXYGEN BY QUALIFIED PERSONNEL. GET MEDICAL ATTENTION. EYES: FLUSH WITH WATER, CONTINUE WASHING FOR SEVERAL MINUTES. REMOVE CONTACT LENSES. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND WATER. IF IRRITATION PERSISTS OR IF CONTACT HAS BEEN PROLONGED, GET MEDI CAL ATTENTION. SWALLOWING: IF PATIENT IS FULLY CONSCIOUS, GIVE TWO GLASSES OF WATER. INDUCE VOMITING. THIS SHOULD BE DONE ONLY BY MEDICAL OR EXPERIENCED FIRST-AID PERSONNEL. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point Method:TCC Flash Point:=11.7C, 53.F Lower Limits:2.0 Upper Limits:12.7 Extinguishing Media:APPLY ALCOHOL-TYPE OR ALL-PURPOSE-TYPE FOAM BY MANUFACTURER'S RECOMMENDED TECHNIQUES FOR LARGE FIRES. USE CARBON DIOXIDE OR DRY CHEMICAL MEDIA FOR SMALL FIRES. Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS AND STRUCTURES. USE WATER SPRAY TO DISPERSE VAPORS; RE-IGNITION IS POSSIBLE. USE SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING. Unusual Fire/Explosion Hazard:PRODUCT VAPORS MAY TRAVEL OR BE MOVED BY AIR CURRENTS AND IGNITED BY PILOT LIGHTS, OTHER IGNITION SOURCES AT LOCATIONS DISTANT FROM PRODUCT HANDLING POINT. VAPORS FROM THIS MATERIAL MAY SETTLE IN LOW OR CONFINED AREAS OR TRAVEL A LONG DISTANCE TO AN IGNITION SOURCE AND FLASHBACK EXPLOSIVELY. ================== Accidental Release Measures ================== Spill Release Procedures:EXTINGUISH IGNITION SOURCE UNTIL AREA IS DETERMINED TO BE FREE FROM FIRE OR EXPLOSION HAZARD. SMALL SPILLS CAN BE FLUSHED WITH LARGE AMOUNTS OF WATER, LARGER SPILLS SHOULD BE COLLECTED FOR DISPOSAL. P ERSONAL PRECAUTIONS: AVOID CONTACT WITH EYES. WEAR SUITABLE PROTECTIVE EQUIPMENT. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS , FLAMES. AVOID CONTACT WITH EYES. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. VAPORS MAY TRAVEL OR MOVED BY AIR CURRENTS AND IGNITED BY PILOT LIGHTS, OTHER IGNIT ION SOURCES DISTANT FROM HANDLING POINT AND FLASHBACK EXPLOSIVELY. WASH THOROUGHLY AFTER HANDLING. Other Precautions:VAPOR MAY SETTLE IN LOW OR CONFINED AREAS, OR TRAVEL A LONG DISTANCE TO AN IGNITION SOURCE AND FLASH BACK EXPLOSIVELY. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE SELF-CONTAINED BREATHING APPARATUS IN HIGH VAPOR CONCENTRATIONS. Ventilation:GENERAL (MECHANICAL) ROOM VENTILATION IS EXPECTED TO BE SATISFACTORY WHERE PRODUCT IS STORED AND HANDLED IN CLOSED EQUIPMENT. (CONTD.SEE SUPPLEMENTAL) Protective Gloves:PLASTIC, RUBBER. Eye Protection:MONOGOGGLES. Other Protective Equipment:EYE BATH, SAFETY SHOWER. Supplemental Safety and Health (CONTD FROM VENTILATION) SPECIAL, LOCAL VENTILATION IS NEEDED AT POINTS WHERE VAPORS CAN BE EXPECTED TO ESCAPE TO THE WORKPLACE AIR. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:=82.3C, 180.1F Melt/Freeze Pt:=-88.3C, -127.F Vapor Pres:4.4 KPA (33 MMHG) Vapor Density:2.1 Spec Gravity:0.787 (H2O=1) 20C/20C VOC Pounds/Gallon:785 Solubility in Water:100%@ 20C Appearance and Odor:TRANSPARENT COLORLESS LIQUID, SLIGHT ETHANOL/ACETONE-LIKE ODOR Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS. HALOGENS. STRONG INORGANIC ACIDS. ALDEHYDES. HALOGEN COMPOUNDS. Hazardous Decomposition Products:CARBON MONOXIDE AND/OR CARBON DIOXIDE. CARBON MONOXIDE IS HIGHLY TOXIC IF INHALED; CARBON DIOXIDE IN SUFFICIENT CONCENTRATIONS CAN ACT AS AN ASPHYXIANT. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:ACUTE TOXICITY: PERORAL: RAT, LD50: 6.48 (4.80-8.76) ML/KG. MAJOR SIGNS: UNSTEADY GAIT, PROSTRATION, HEAVY BREATHING. GROSS PATHOLOGY: LUNGS AND ABDOMINAL VISCERA DISCOLORED. PERCUTANEOUS: RABBIT LD50 24 HR OCCLUDED 8.0 (4.9-13.1 ML/KG. GROSS PATHOLOGY: LUNGS, LIVER, STOMACH DISCOLORED. INHALATION: STATIC GENERATION OF VAPOR EXPOSURE TIME 2 H, RABBIT, ROOM TEMPERATURE, KILL RATE:4/6, MAJOR SIGNS: LACRIMATION, LOSS OF COORDINATION, PROSTATION. GROSS PATHOLOGY: LUNGS DISCOLORED. THERE ARE FOUR MORE INHALATION AND ONE MORE IRRITATION TEST RESULTS ON THE MANUFACTURER'S MSDS BUT SPACE NOT AVAILABL E TO INCLUDE HERE. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: BOD (% OXYGEN CONSUMPTION): DAY5=28%; DAY 10=77%; DAY 20=78%. ECOTOXICITY TO MICRO-ORGANISMS:BACTERIAL/NA IC50 5000 MG/L. ECOTOXICITY TO AQUATIC INVEREBRATES: DAPHNIA LC50 48 H 755 0 MG/L. ECOTOXICITY TO FISH: FATHEAD MINNOW LC50 96 H 8300 MG/L. FURTHER INFORMATION: TI IOD (MEASURED) 2.30 MG/MG. TI IOD (CALCULATED) 2.40 MG/MG. OCTANOL/WATER PARTITION COEFFICIENT-MEASURED: 0.14. ==================== Disposal Considerations ==================== Waste Disposal Methods:INCINERATE IN FURNACE IF PERMITTED UNDER FEDERAL, STATE, LOCAL REGULATIONS. DISPOSE IN ACCORDANCE WITH APPLICABLE FEDERAL, STATE, PROVINCIAL, LOCAL ENVIRONMENTAL REGULATIONS. EMPTY CONTAINERS SHOULD B E RECYCLED OR DISPOSED OF THROUGH APPROVED WASTE MANAGEMENT FACILITY. PRODUCT IS BIODEGRADABLE IN BI OLOGICAL WASTEWATER TREATMENT PLANT. =================== MSDS Transport Information =================== Transport Information:U.S. D.O.T.: NON-BULK: PROPER SHIPPING NAME: ISOPROPANOL; UN 1219: HAZARD CLASS: 3; PKG: I I. BULK: PROPER SHIPPING NAME: ISOPROPANOL; UN1219; HAZARD CLASS: 3; PKG: I I. ADDITIONAL TRANSPORTATION SYST EM INFORMATION CAN BE OBTAINED THROUGH YOUR UCC SALES OR CUSTOMER SERVICE REPRESENTATIVE. ===================== Regulatory Information ===================== SARA Title III Information:SECTIONS 302 AND 304: NONE OF THE COMPONENTS OF THIS PRODUCT ARE LISTED AS EXTREMELY HAZARDOUS SUBSTANCES IN 40 CFR PART 355 AND ARE PRESENT AT LEVELS WHICH COULD REQUIRE REPORTING AND EMERGENCY PLANN ING. SECTION 313: NONE OF THE COMPONENTSOF THIS PRODUCT ARE LISTED AS TOXIC CHEMICALS IN 40 CFR 372.65 AND ARE PRESENT AT LEVELS WHICH COULD REQUIRE REPORTING AND CUSTOMER NOTIFICATION UNDER SECTION 3 13 AND 40 CFR PART 372. SECTION 311 AND 312: DELAYED HAZARD: YES; FIRE HAZARD: YES; IMMEDIATE HEALTH HAZARD: YES; REACTIVE HAZARD; NO; SUDDEN RELEASE OF PRESSURE HAZARD: NO. Federal Regulatory Information:CERCLA:SECTION 103: NO COMPONENTS OF THIS PRODUCT ARE LISTED AS HAZARDOUS SUBSTANCES IN 40 CFR 302.4 (UNLISTED HAZARDOUS SUBSTANCES NOT IDENTIFIED) AND PRESENT AT LEVELS WHICH COULD REQUIRE REPORTING. TOXIC SUBSTANCES CONTROL ACT (TSCA):ALL COMPONENTS OF THIS PRODUCT ARE ON TSCA INVENTORY OR ARE EXEMPT FROM TSCA INVENTORY REQUIREMENTS. CONTD. FROM STATE)NO LISTED SUBSTANCES KNOWN TO CALIFORNIA TO C AUSE CANCER, BIRTH DEFECTS, OTHER REPRODUCTIVE HARM, AT LEVELS WHICH WOULD REQUIRE A WARNING UNDER T HIS STATUTE. CA. SCAQMD RULE 443.1: VOC: 785 G/L VAPOR PRESSURE 33MMHG @ 20C. State Regulatory Information:PENNSYLVANIA: THIS PRODUCT IS SUBJECT TO THE WORKER AND COMMUNITY RIGHT-TO-KNOW ACT. THE FOLLOWING COMPONENTS OF THIS PRODUCT ARE AT LEVELS WHICH COULD REQUIRE IDENTIFICATION IN THE MSDS: ISOPROPANOL, CAS# 67-63-0, <=100.0%. MASSACHUSETTS (HAZARDOUS SUBSTANCES DISCLOSURE BY EMPLOYERS): THE FOLLOWING COMPONENTS OF THIS PRODUCT APPEAR ON THE MASSACHUSETTS SUBSTANCE LIST AND ARE PRESENT AT LEVELS WHI CH COULD REQUIRE IDENTIFICATION IN THE MSDS: ISOPROPANOL; CAS# 67-63-0; <=100.0%. CALIFORNIA PROPOSI TION 65 (SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986): THIS PRODUCT CONTAINS (CONTD.TO FEDERAL) ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.