COLUMBUS CHEMICAL INDUSTRIES INC -- CYCLOHEXANE -- 6810-00-492-5589
===================== Product Identification ===================== Product ID:CYCLOHEXANE MSDS Date:09/13/1995 FSC:6810 NIIN:00-492-5589 === Responsible Party === Company Name:COLUMBUS CHEMICAL INDUSTRIES INC Address:N 4335 TEMKIN RD City:COLUMBUS State:WI ZIP:53925 Country:US Info Phone Num:414-623-2140 / FAX 414-623-2577 Emergency Phone Num:414-623-2140 CAGE:5Y144 === Contractor Identification === Company Name:CHEM SCIENTIFIC INC Address:1250 WASHINGTON ST Box:City:NORWOOD State:MA ZIP:02062 Country:US Phone:781-440-0900 CAGE:0X801 Company Name:COLUMBUS CHEMICAL INDUSTRIES INC Address:N 4335 TEMKIN RD Box:8 City:COLUMBUS State:WI ZIP:53925-0008 Country:US Phone:920-623-2140 CAGE:5Y144 ============= Composition/Information on Ingredients ============= Ingred Name:CYCLOHEXANE (SARA 313) (CERCLA) CAS:110-82-7 RTECS #:GU6300000 Fraction by Wt: 100% Other REC Limits:NONE RECOMMENDED OSHA PEL:300 PPM ACGIH TLV:300 PPM, 9596 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:BENZENE (SARA 313) (CERCLA) CAS:71-43-2 RTECS #:CY1400000 Fraction by Wt: < .1% Other REC Limits:NONE RECOMMENDED OSHA PEL:SEE 1910.1028 ACGIH TLV:10 PPM; A2; 9596 EPA Rpt Qty:10 LBS DOT Rpt Qty:10 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:ORAL LD50 (RATS): > 5 G/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:NOT EXPECTED TO CAUSE PROLONGED OR SIGNIFICANT EYE IRRITATION. PROLONGED OR FREQUENT SKIN CONTACT MAY CAUSE SKIN CRACKING/DRYING/DEFATTING. IF SWALLOWED, SUBSTANCE CONSIDERED PRACTICALLY NONTOXIC. ASP IRATION HAZARD. BREATHING VAPORS AT CONCENTRATIONS ABOVE RECOMMENDED STANDARD CAN CAUSE CNS EFFECTS. Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT CARCINOGENS. Effects of Overexposure:CENTRAL NERVOUS SYSTEM EFFECTS MAY INCLUDE ONE OR MORE OF THE FOLLOWING: HEADACHE, DIZZINESS, LOSS OF APPETITE, WEAKNESS, LOSS OF COORDINATION. EYE IRRITATION, SKIN IRRITATION, SKIN DEFATTING/DRYING/C RACKING. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER. IF IRRITATION PERSIST, GET MEDICAL ATTENTION. INH ALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION. GIVE MILK OR WATER TO DRINK. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:>-1F,>-18C Autoignition Temp:Autoignition Temp Text:500F Lower Limits:1.3 % Upper Limits:8.3 % Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR. PRODUCT IS EXTREMELY FLAMMABLE. LIQUID VERY QUICKLY EVAPORATES Unusual Fire/Explosion Hazard:INVISIBLE VAPOR SPREADS EASILY AND CAN BE SET ON FIRE BY MANY SOURCES SUCH AS PILOT LIGHTS, WELDING EQUIPMENT, ELECTRICAL MOTORS, SWITCHES. ================== Accidental Release Measures ================== Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION . STOP SOURCE OF LEAK. CLEAN UP RELEASES AS SOON AS POSSIBLE. CONTAIN LIQUID TO PREVENT FURTHER CONTAMINATION OF SOIL, SURFACE WATER OR GROUNDWATER. CLEAN UP SMALL SP ILLS USING APPROPRIATE TECHNIQUES. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:DO NOT USE OR STORE NEAR FLAME, SPARKS OR HOT SURFACES. USE ONLY IN WELL VENTILATED AREA. KEEP CONTAINER CLOSED. DO NOT WELD, HEAT OR DRILL CONTAINER. Other Precautions:REPLACE CAP OR BUNG. EMPTIED CONTAINER STILL CONTAINS HAZARDOUS OR EXPLOSIVE VAPOR OR LIQUID. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATION EXPOSURE LIMITS USE A NIOSH-APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE. IN ACCORD WITH 29 CFR 1910.134 USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AI R-PURIFYING RESPIRATOR. Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP AIRBORNE CONCENTRATIONS BELOW RESPECTIVE TLV'S. Protective Gloves:NONE NORMALLY REQUIRED. Eye Protection:CHEMICAL GOGGLES, SAFETY GLASSES W/SIDES Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE. Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. Supplemental Safety and Health REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. ================== Physical/Chemical Properties ================== HCC:F2 Boiling Pt:B.P. Text:177F,81C Melt/Freeze Pt:M.P/F.P Text:37.0F,2.8C Decomp Temp:Decomp Text:NOT GIVEN Vapor Pres:175 Vapor Density:2.9 Spec Gravity:0.78 Viscosity:32.6 Evaporation Rate & Reference:1.95 (NO REFERENCE GIVEN) Solubility in Water:INSOLUBLE Appearance and Odor:COLORLESS, MOBILE LIQUID WITH SWEETISH ODOR RESEMBLING THAT OF CHLOROFORM Percent Volatiles by Volume:100% ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS SUCH AS CHLORATES, NITRATES, PEROXIDES, ETC. Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN ==================== Disposal Considerations ==================== Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS. 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